|
|
ATP + geranylgeranyl_phosphate <=> ADP + geranylgeranyl_diphosphate
|
2.7.4.B4
|
–
|
|
BRENDA:
BR50488
|
|
|
|
(2E,6E)-farnesyl_diphosphate + isopentenyl_diphosphate <=> geranylgeranyl_diphosphate + diphosphate
|
2.5.1
2.5.1.29
geranylgeranyl diphosphate synthase
|
–
–
|
|
BRENDA:
BR47565
KEGG:
R02061;
R05555
MetaCyc:
FARNESYLTRANSTRANSFERASE-RXN;
RXN0-5180
SABIO-RK:
2078
|
|
|
|
2-phospho-4-(cytidine_5''-diphospho)-2-C-methyl-D-erythritol <=> 2-C-methyl-D-erythritol_2,4-cyclodiphosphate + CMP
|
4.6.1.12
2-C-methyl-D-erythritol 2,4-cyclodiphosphate synthase
|
–
|
|
BRENDA:
BR26153
KEGG:
R05637
MetaCyc:
RXN0-302
SABIO-RK:
5235
|
|
|
|
geranylgeranyl_diphosphate + isopentenyl_diphosphate <=> all-trans-hexaprenyl_diphosphate + diphosphate
|
2.5.1.82
hexaprenyl diphosphate synthase [geranylgeranyl-diphosphate specific]
2.5.1.B41
|
–
–
|
|
BRENDA:
BR49312
KEGG:
R09246
MetaCyc:
RXN-11485
|
|
|
|
(2E,6E)-farnesyl_diphosphate + isopentenyl_diphosphate <=> di-trans,poly-cis-nonaprenyl_diphosphate + diphosphate
|
2.5.1.84
all-trans-nonaprenyl diphosphate synthase [geranyl-diphosphate specific]
2.5.1.85
all-trans-nonaprenyl diphosphate synthase [geranylgeranyl-diphosphate specific]
2.5.1.87
ditrans,polycis-polyprenyl diphosphate synthase [(2E,6E)-farnesyl diphosphate specific]
2.5.1.B14
|
–
–
–
–
|
|
BRENDA:
BR49316;
BS406946
MetaCyc:
RXN-21510
|
|
|
|
(2E,6E,10E,14E)-geranylfarnesyl_diphosphate + H2O <=> ophiobolin_F + diphosphate
|
4.2.3.145
ophiobolin F synthase
|
–
|
|
BRENDA:
BR51059
KEGG:
R10762
MetaCyc:
RXN-15427
|
|
|
|
geranylgeranyl_diphosphate <=> prephytoene_diphosphate + diphosphate
|
2.5.1.148
lycopaoctaene synthase
2.5.1.32
15-cis-phytoene synthase
|
–
–
|
|
BRENDA:
BR47500
KEGG:
R02065
MetaCyc:
2.5.1.32-RXN
SABIO-RK:
2081
|
|
|
|
H+ + 2-C-methyl-D-erythritol_4-phosphate + CTP <=> 4-(cytidine_5''-diphospho)-2-C-methyl-D-erythritol + diphosphate
|
2.7.7.60
2-C-methyl-D-erythritol 4-phosphate cytidylyltransferase
|
–
|
|
BRENDA:
BR36947
KEGG:
R05633
MetaCyc:
2.7.7.60-RXN
SABIO-RK:
5231
|
|
|
|
geranyl_diphosphate + isopentenyl_diphosphate <=> (2E,6E)-farnesyl_diphosphate + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
2.5.1.10
(2E,6E)-farnesyl diphosphate synthase
2.5.1.29
geranylgeranyl diphosphate synthase
|
–
–
–
|
|
BRENDA:
BR47562
KEGG:
R02003
MetaCyc:
FPPSYN-RXN
SABIO-RK:
2041
|
|
|
|
H+ + pyruvate + D-glyceraldehyde_3-phosphate <=> 1-deoxy-D-xylulose_5-phosphate + CO2
|
2.2.1.7
1-deoxy-D-xylulose-5-phosphate synthase
|
–
|
|
BRENDA:
BR37092;
BS260856
KEGG:
R05636
MetaCyc:
DXS-RXN
|
|
|
|
isopentenyl_diphosphate + geranylgeranyl_diphosphate <=> (2E,6E,10E,14E)-geranylfarnesyl_diphosphate + diphosphate
|
2.5.1.81
geranylfarnesyl diphosphate synthase
2.5.1.B41
|
–
–
|
|
BRENDA:
BR48628
KEGG:
R07475
MetaCyc:
RXN-8813
|
|
|
|
ATP + geranylgeraniol <=> ADP + geranylgeranyl_phosphate + H+
|
2.7.1.216
farnesol kinase
2.7.1.66
undecaprenol kinase
2.7.1.B19
|
–
–
–
|
|
BRENDA:
BR50486
MetaCyc:
RXN-12325
|
|
|
|
geranylgeranyl_diphosphate + H2O <=> cyclooctat-9-en-7-ol + diphosphate
|
4.2.3.146
cyclooctat-9-en-7-ol synthase
|
–
|
|
BRENDA:
BR51060
KEGG:
R10763
MetaCyc:
RXN-15429
|
|
|
|
2-C-methyl-D-erythritol_4-phosphate + NADP+ <=> 1-deoxy-D-xylulose_5-phosphate + NADPH + H+
|
1.1.1.267
1-deoxy-D-xylulose-5-phosphate reductoisomerase
|
–
|
|
BRENDA:
BR29286
KEGG:
R05688
MetaCyc:
DXPREDISOM-RXN
SABIO-RK:
5284
|
|
|
|
(2E,6E)-farnesyl_diphosphate + isopentenyl_diphosphate <=> di-trans-poly-cis-decaprenyl_diphosphate + diphosphate
|
2.5.1.87
ditrans,polycis-polyprenyl diphosphate synthase [(2E,6E)-farnesyl diphosphate specific]
2.5.1.91
all-trans-decaprenyl-diphosphate synthase
|
–
–
|
|
BRENDA:
BR49323
KEGG:
R09249
MetaCyc:
RXN-21509;
RXN-9106
|
|
|
|
(2E,6E)-farnesyl_diphosphate + isopentenyl_diphosphate <=> all-trans-heptaprenyl_diphosphate + diphosphate
|
2.5.1.30
heptaprenyl diphosphate synthase
2.5.1.B41
|
–
–
|
|
BRENDA:
BR47476
KEGG:
R09247
MetaCyc:
TRANS-HEXAPRENYLTRANSTRANSFERASE-RXN
SABIO-RK:
13830
|
|
|
|
phytyl_diphosphate + NADP+ <=> geranylgeranyl_diphosphate + NADPH + H+
|
1.3.1.83
geranylgeranyl diphosphate reductase
|
–
|
|
BRENDA:
BR49043
KEGG:
R02063
MetaCyc:
RXN-10625
|
|
|
|
geranyl_diphosphate + isopentenyl_diphosphate <=> nonaprenyl_diphosphate + diphosphate
|
2.5.1.84
all-trans-nonaprenyl diphosphate synthase [geranyl-diphosphate specific]
|
–
|
|
BRENDA:
BR49314
KEGG:
R09250
MetaCyc:
TRANS-OCTAPRENYLTRANSTRANSFERASE-RXN
|
|
|
|
dimethylallyl_diphosphate + isopentenyl_diphosphate <=> geranyl_diphosphate + diphosphate
|
2.5.1.1
dimethylallyltranstransferase
2.5.1.10
(2E,6E)-farnesyl diphosphate synthase
2.5.1.29
geranylgeranyl diphosphate synthase
2.5.1.67
chrysanthemyl diphosphate synthase
2.5.1.69
lavandulyl diphosphate synthase
|
–
–
–
–
–
|
|
BRENDA:
BR47563
KEGG:
R01658
MetaCyc:
GPPSYN-RXN
SABIO-RK:
1793
|
|
|
|
(E)-4-hydroxy-3-methylbut-2-en-1-yl_diphosphate + oxidized_ferredoxin + H2O <=> 2-C-methyl-D-erythritol_2,4-cyclodiphosphate + reduced_ferredoxin_[iron-sulfur]_cluster + H+
|
1.17.7.1
(E)-4-hydroxy-3-methylbut-2-enyl-diphosphate synthase (ferredoxin)
|
–
|
|
BRENDA:
BR47612
KEGG:
R08689
MetaCyc:
RXN0-882
|
|
|
|
geranyl_diphosphate + H2O <=> geraniol + diphosphate
|
3.1.7.11
geranyl diphosphate diphosphatase
3.1.7.3
monoterpenyl-diphosphatase
4.2.3.104
alpha-humulene synthase
|
–
–
–
|
|
BRENDA:
BR50059
KEGG:
R08396
MetaCyc:
RXN-17103;
RXN-8618
SABIO-RK:
12967
|
|
|
|
geranylgeranyl_diphosphate + isopentenyl_diphosphate <=> nonaprenyl_diphosphate + diphosphate
|
2.5.1.84
all-trans-nonaprenyl diphosphate synthase [geranyl-diphosphate specific]
2.5.1.85
all-trans-nonaprenyl diphosphate synthase [geranylgeranyl-diphosphate specific]
|
–
–
|
|
BRENDA:
BR49315
KEGG:
R09251
MetaCyc:
RXN-11486
|
|
|
|
4-(cytidine_5''-diphospho)-2-C-methyl-D-erythritol + ATP <=> H+ + 2-phospho-4-(cytidine_5''-diphospho)-2-C-methyl-D-erythritol + ADP
|
2.7.1.148
4-(cytidine 5'-diphospho)-2-C-methyl-D-erythritol kinase
|
–
|
|
BRENDA:
BR33803
KEGG:
R05634
MetaCyc:
2.7.1.148-RXN
|
|
|
|
(E)-4-hydroxy-3-methylbut-2-en-1-yl_diphosphate + NADPH <=> dimethylallyl_diphosphate + isopentenyl_diphosphate + NADP+ + H2O
|
1.17.7.4
4-hydroxy-3-methylbut-2-en-1-yl diphosphate reductase
|
–
|
|
BRENDA:
BS427790
|
|
|
|
geraniol + NAD+ <=> citral + NADH + H+
|
1.1.1.1
alcohol dehydrogenase
1.1.1.183
geraniol dehydrogenase (NADP+)
1.1.1.198
(+)-borneol dehydrogenase
1.1.1.347
geraniol dehydrogenase (NAD+)
1.1.1.90
aryl-alcohol dehydrogenase
|
–
–
–
–
–
|
|
BRENDA:
BR50498
KEGG:
R10308
MetaCyc:
RXN-11968
SABIO-RK:
13273
|
|
|
|
geranylgeranyl_diphosphate + isopentenyl_diphosphate <=> tritrans,heptacis-undecaprenyl_diphosphate + diphosphate
|
2.5.1.89
tritrans,polycis-undecaprenyl diphosphate synthase [geranylgeranyl-diphosphate specific]
|
–
|
|
BRENDA:
BR49320
KEGG:
R09730
MetaCyc:
RXN-11488
|
|